Regioselective acylation of (5-alkylidene-1,3-cyclohexadiene)tricarbonyliron complexes by the reaction with organometallic reagents

Article abstract of DOI:10.1246/cl.1998.395

Reaction of [(1,2,3,4-η)-5-alkylidene-1,3-cyclohexadiene]-tricarbonylirons and organometallic reagents generates acyl-[(1,2,3,4,5-η)-1-alkylcydohexadienyl]dicarbonylirons. The acyl group in these complexes migrates to the cyclohexadienyl moiety under carb