Novel Ring-opening Reaction of Norbornadiene(tricarbonyl)iron; Synthesis and Crystal Structure of C7H8(CO)2FeC(OEt)Ar

DOI: 10.1039/c39880001296

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1296 - 1298 (1988)

Update date:2022-08-17

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Authors:

Chen, Jiabi

Lei, Guixin

Shao, Meicheng

Xu, Xiaojie

Zhang, Zeying

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Article abstract of DOI:10.1039/c39880001296

Reaction of norbornadiene(tricarbonyl)iron with aryl-lithium reagents at low temperature, followed by alkylation of the intermediate acylmetallates with Et3OBF4 in aqueous solution at 0 deg C gives novel ring-opened diallyl complexes, C7H8(CO)2FeC(OC2H5)A

Full text of DOI:10.1039/c39880001296

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Product name:C₇H₈Fe(CO)3C(OEt)(p-CF₃C₆H₄)

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