The study of the reaction between thiophosphoryl esters and boron tribromide. The synthesis of oxathiaphosphaboretanes

Article abstract of DOI:10.1080/10426500008045215

Reactions between three thiophosphoryl esters and boron tribromide are reported. O,O,O-triethyl phosphorothionate (1) and O,O-diethyl methanephosphonothionate (5) gave substituted oxathiaphosphaboretanes 4 and 7 respectively. O-methyl diphenyl-phosphinothionate (9) led to the complex 11 and the corresponding oxathiaphosphaboretane 12. In order to establish the mechanism, reactions were monitored by the multinuclear NMR spectroscopy.

Full text of DOI:10.1080/10426500008045215

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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THE STUDY OF THE
REACTION BETWEEN
THIOPHOSPHORYL ESTERS
AND BORON TRIBROMIDE.
THE SYNTHESIS OF
OXATHIAPHOSPHABORETANES
Jarosław Lewkowski a , Jacques Mortier b & Michel
Vaultier b
a Department of Organic Chemistry , University of
Lódź , Narutowicza 68, 90-136, Lódź, POLAND
b Synthèse et Electrosynthèse Organique, UMR
6510 associe au CNRS, Université Rennes 1 , 35042,
Rennes, Cedex, FRANCE
Published online: 04 Oct 2006.
To cite this article: Jarosław Lewkowski , Jacques Mortier & Michel Vaultier (2000)
THE STUDY OF THE REACTION BETWEEN THIOPHOSPHORYL ESTERS AND BORON
TRIBROMIDE. THE SYNTHESIS OF OXATHIAPHOSPHABORETANES, Phosphorus, Sulfur, and
Silicon and the Related Elements, 162:1, 1-14, DOI: 10.1080/10426500008045215
To link to this article: http://dx.doi.org/10.1080/10426500008045215
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