Journal of the Chemical Society - Faraday Transactions p. 2215 - 2220 (1992)
Update date:2022-08-11
Topics:
Inoue, Hiroshi
Yamachika, Mikio
Yoneyama, Hiroshi
The photocatalytic fixation of CO2 in pyruvic acid to yield malic acid has been achieved in TiO2 microcrystal and CdS particle suspensions using malic enzyme as the catalyst, methyl viologen as the electron mediator and either 2-mercaptoethanol or lactic acid as the hole scavenger.The evaluation of the rate-determining step in the photocatalytic fixation reaction was made at the TiO2 microcrystal for the case of 2-mercaptoethanol as the hole scavenger.The use of lactic acid as the hole scavenger resulted in the selective photoproduction of pyruvic acid at the CdS photocatalyst, a fraction of which was then converted into malic acid by reductive CO2 fixation at the malic enzyme.However, it has been found that lactic acid causes a decrease in the catalytic activities of the enzyme, the degree depending on the relative concentrations of malic enzyme and lactic acid.
View MoreFeis International Trade Co,. Ltd
Contact:13961823444-18235944442
Address:Wuxi jiangsu
shanghai jiuling chemical co.,ltd.
Contact:+86-21-50387295
Address:Zaozhuang Road, Pudong, Shanghai City. China
Jurong Huaheng Natural Biological Products Factory
website:http://www.risebiochem.com
Contact:+86-13921007726
Address:Chuncheng town,Jurong city,Jiangsu province,China
Lianyungang Ningkang Chemical Co., Ltd
Contact:.+86-518-88588008
Address:http://www.chemnk.com
HANGZHOU GOPHER CHEM-TECH CO.,LTD
Contact:86-189-58111780
Address:Da Cheng Ming Zuo Plaza,Xiaoshan District
Doi:10.1016/j.tca.2012.04.018
(2012)Doi:10.1016/0031-9422(90)85170-K
(1990)Doi:10.1021/ja01858a032
(1940)Doi:10.1021/ja00998a032
(1967)Doi:10.1055/s-2007-991089
(2007)Doi:10.1055/s-0034-1379319
(2015)
