Multiple Reductive Cleavage of Calixarene Diethyl Phosphate Esters: a Route to n>metacyclophanes

DOI: 10.1039/P19900001484

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1484 - 1487 (1990)

Update date:2022-08-11

Topics:

Authors:

Goren, Zafrir

Biali, Silvio E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19900001484

The OH groups of p-t-butylcalixarene (n = 4 and 8) were converted into diethyl phosphate esters and reductively cleaved by treatment with K/NH3 to yield tetra-p-t-butyl<1⁴>- and octa-p-t-butyl<1⁸>metacyclophanes (4) and (7).

Full text of DOI:10.1039/P19900001484

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:25,26-bis-O-(diethoxyphosphoryl)(p-tert-butyl)calix[4]arene

Cas No:128910-39-4

R&D Labs maybe for 128910-39-4

Maithili Life Sciences

Contact:+91 9963263336

Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Nowa pharmaceuticals Co., LTD

Contact:86-512-69362780,69362785

Address:No.69 Weixin Road,Weiting Town,Suzhou Industrial Park
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
BioBioPha Co., Ltd

Contact:+86-871-65217109

Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences
Suzhou Time-chem Technologies Co., Ltd.

Contact:0512-63983931/68086856

Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China

Relevant to this article

Minor constituents of Spigelia anthelmia and their cardiac activities

Doi:10.1016/S0031-9422(01)00020-6
(2001)
One-pot synthesis of sulfides by reaction of disulfides with alkyl halides in the presence of sodium dithionite

Doi:10.1080/10426500600892479
(2007)
Stereospecific 1,3-Aminobromination of Donor–Acceptor Cyclopropanes

Doi:10.1002/anie.201704092
(2017)
A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: Molecular structures of {Ru(dppe)Cp*} ₂(μ-C₁₄) and {Co₃(μ-dppm)(CO) ₇}₂(μ₃:μ₃-C₁₆)

Doi:10.1039/b315854n
(2004)
A new monoterpenoid glycoside from Myrica esculenta and the inhibition of angiotensin I-converting enzyme

Doi:10.1248/cpb.58.1408
(2010)
Photochemical chlorination and oxygenation reaction of cyclohexene sensitized by Ga(III) porphyrin clay minerals system with high durability and usability

Doi:10.1246/bcsj.20140378
(2015)

Article Doi