
Journal of the American Chemical Society p. 11928 - 11929 (2005)
Update date:2022-08-16
Topics:
Takahashi, Tamotsu
Liu, Yuanhong
Iesato, Atsushi
Chaki, Shinji
Nakajima, Kiyohiko
Kanno, Ken-Ichiro
The reaction of diarylalkynes with Cp2ZrBu2 and successive treatment with CrCl3 afforded linear tetramers of diarylalkynes, (1E,3E,5E,7E)-octatetraenes. On the other hand, dialkylalkynes did not give the corresponding octatetraenes but cyclized products, such as pyridines and pyridones, by the reaction with nitriles and isocyanates. Copyright
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