Journal of the Chemical Society. Chemical communications p. 681 - 683 (1984)
Update date:2022-08-16
Topics:
Grevels, Friedrich-Wilhelm
Skibbe, Volker
(η2-Olefin)nCr(CO)6-n complexes result from the photoreactions of Cr(CO)6 with cis-cyclo-octene (n = 1) and trans-cyclo-octene (n = 1, 2); (η2-cis-cyclo-octene)Cr(CO)5, isolated as yellow solid, is labile in solution and serves as a useful Cr(CO)5 transfer reagent to produce various LCr(CO)5 derivatives, including the isotopically labelled hexacarbonyl, Cr(CO)5(13CO).
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