Dioxalanones as synthetic intermediates. Part 6. Synthesis of 3-deoxy-D-manno-2-octulosonic acid (KDO), 3-Deoxy-D-Arabino-2-Heptulosonic acid (DAH) and 2-Keto-3-Deoxy-D-Gluconic acid (KDG)

DOI: 10.1016/S0040-4020(01)80993-5

Source and publish data:

Tetrahedron p. 5625 - 5636 (1991)

Update date:2022-08-29

Topics:

Authors:

Ramage, Robert

MacLeod, Angus M.

Rose, Graeme W.

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Article abstract of DOI:10.1016/S0040-4020(01)80993-5

Three biosynthetically significant α-keto acids KDO (7), DAH (8) and KDG (9) have been synthesised via 5-ylidene-1,3-dioxalan-4-one intermediates formed by Wittig reactions of protected monosaccharide-derived aldehydes with the Wittig reagent (3).

Full text of DOI:10.1016/S0040-4020(01)80993-5

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Product name:(4S)-2,2-Dimethyl-5β-[(4R)-2,2-dimethyl-1,3-dioxolane-4β-yl]-1,3-dioxolane-4α-carbaldehyde

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