Lewis acid supported reactions of 1,3-bis(silyl)allyl compounds with epoxides - Inter- and intramolecular versions

DOI: 10.1016/S0040-4039(97)10675-X

Source and publish data:

Tetrahedron Letters p. 529 - 532 (1998)

Update date:2022-08-30

Topics:

Authors:

Nowak, Anette

Bolte, Oliver

Schaumann, Ernst

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Article abstract of DOI:10.1016/S0040-4039(97)10675-X

Easily available 1,3-bis(silyl)allyl compounds react with epoxides under Lewis acid catalysis to give interesting synthetic building blocks. The course of reaction depends on the stabilization of cationic intermediates by the silicon β-effect.

Full text of DOI:10.1016/S0040-4039(97)10675-X

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