Asymmetric Synthesis of Phenyl Alkyl Sulphoxides via the Non-destructive Mediation of the Chiral Iron Acyl 5-C5H5)Fe(CO)(PPh3)COCH2Me>

DOI: 10.1039/c39880000780

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 780 - 781 (1988)

Update date:2022-08-11

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Authors:

Davies, Stephen G.

Gravatt, G. Lance

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Article abstract of DOI:10.1039/c39880000780

The chiral sulphoxide (RSS)-<(η⁵-C5H5)Fe(CO)(PPh3)COCHMeSOPh> can be efficiently and stereoselectively prepared from (R)-<(η⁵-C5H5)Fe(CO)(PPh3)COCH2Me> via the asymmetric oxidation of the corresponding sulphide: treatment of (RSS)-<(

Full text of DOI:10.1039/c39880000780

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