Reaction of singlet oxygen with thietane. A novel example of a self-catalyzed reaction which provides evidence for a thiadioxirane intermediate

DOI: 10.1021/ja00144a003

Source and publish data:

Journal of the American Chemical Society p. 9800 - 9803 (1995)

Update date:2022-08-30

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Authors:

Clennan, Edward L.

Dobrowolski, Piotr

Greer, Alexander

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Article abstract of DOI:10.1021/ja00144a003

Singlet oxygen reacts with thietane, 1, to give the sulfoxide, 1SO, and a trace of sulfone, 1SO₂. A mechanism which involves a novel substrate catalyzed interconversion of a persulfoxide and thiadioxirane intermediate is proposed. The data whic

Full text of DOI:10.1021/ja00144a003

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