Tetrahedron Letters p. 5545 - 5548 (1998)
Update date:2022-08-17
Topics:
Koh, Jeong Hwan
Jeong, Hyun Min
Park, Jaiwook
(η5-Indenyl)RuCl(PPh3)2 was found to efficiently catalyze the racemization of chiral alcohols such as (S)-1-phenylethan-1-ol, (S)-1- phenylpropan-2-ol and (S)-4-phenylbutan-2-ol at room temperature in the presence of base. The catalytic activity of five other Ru(II) complexes was also investigated. The effects of varying reaction conditions such as reaction temperature, solvent, and base were investigated as well.
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