Dalton Transactions p. 12955 - 12959 (2020)
Update date:2022-08-30
Topics:
Dragulescu-Andrasi, Alina
Jo, Minyoung
Li, Jingbai
Rogachev, Andrey Yu
Shatruk, Michael
Cu(i) and Au(i) ions, capped with an N-heterocyclic carbene (NHC), react with (TMS)3P7 (TMS = trimethyl-silyl) to afford an η4-coordinated anion [NHCDippCu-P7(TMS)]- and a neutral trinuclear complex (NHCDippAu)3P7. Protecting the P7 cage with the TMS groups is instrumental in controlling the course of these reactions. This journal is
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