Sulphonyl Transfer Reactions: Solvolysis of Arenesulphonyl Chlorides in Aqueous Trifluoroethanol

DOI: 10.1039/c39910000854

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 854 - 856 (1991)

Update date:2022-08-03

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Authors:

Forbes, Rowena M.

Maskill, H.

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Article abstract of DOI:10.1039/c39910000854

Activation parameters for the solvolysis in aqueous trifluoroethanol of arenesulphonyl chlorides with electron-supplying substituents have been determined; the results are not in accord with earlier proposals that such compounds reacts by an S_N1 mechanism.

Full text of DOI:10.1039/c39910000854

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