Sulphonyl Transfer Reactions: Solvolysis of Arenesulphonyl Chlorides in Aqueous Trifluoroethanol

DOI: 10.1039/c39910000854

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 854 - 856 (1991)

Update date:2022-08-03

Topics:

Authors:

Forbes, Rowena M.

Maskill, H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000854

Activation parameters for the solvolysis in aqueous trifluoroethanol of arenesulphonyl chlorides with electron-supplying substituents have been determined; the results are not in accord with earlier proposals that such compounds reacts by an S_N1 mechanism.

Full text of DOI:10.1039/c39910000854

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:4-Dimethylamino-benzolsulfonsaeure-(2,2,2-trifluor-ethylester)

Cas No:13607-65-3

R&D Labs maybe for 13607-65-3

SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan
Dongguan Albiya Energy Science and Technology Co.,Ltd

Contact:+86-769-22181286

Address:Huanan Industial Park, Dongguan,China

Relevant to this article

Catalytic enantioselective 1,2-diboration of 1,3-dienes: Versatile reagents for stereoselective allylation

Doi:10.1002/anie.201105716
(2012)
Direct Transformations of Ketones to γ-Unsaturated Thiols via [2,3]-Sigmatropic Rearrangement of Allyl Sulfinyl Carbanions: A Combined Experimental and Computational Study

Doi:10.1021/jo991672e
(2000)
NaOH-catalyzed dimerization of monofunctionalized hydrofullerenes: Transition-metal-free, general, and efficient synthesis of single-bonded [60]fullerene dimers

Doi:10.1021/ol301435m
(2012)
A versatile approach to alcohol, aldehyde, ketone and amine derivatives starting from β-allyl C-glycosides of D-ribofuranose and 2-deoxy-D-ribofuranose

Doi:10.1055/s-0030-1260200
(2011)
Synthesis and antibacterial activity of 6-substituted anacardic acid derivatives

Doi:10.2174/157018011797655278
(2011)
A novel BF₂-chelated azadipyrromethene-fullerene dyad: Synthesis, electrochemistry and photodynamics

Doi:10.1039/c1cc16071k
(2012)

Article Doi