HYDROBORATION-CARBONYLATION OF BISOLEFINIC AMINES: A FACILE SYNTHESIS OF δ-CONICEINE

DOI: 10.1016/S0040-4039(01)93280-0

Source and publish data:

Tetrahedron Letters p. 2075 - 2076 (1981)

Update date:2022-08-11

Topics:

Authors:

Garst, Michael E.

Bonfiglio, John N.

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Article abstract of DOI:10.1016/S0040-4039(01)93280-0

Treatment of N-allyl-N-3-butenyl-N-Cbz-amine (1) with thexyl borane followed by cyanidation affords an azacyclononanone 2 in 35 percent yield which can be transformed into δ-coniceine (3) by catalytic reduction.

Full text of DOI:10.1016/S0040-4039(01)93280-0

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