PHOTOCHEMICAL ADDITION OF PERFLUORO-n-BUTYL IODIDE TO ALKYNES AND OLEFINS

DOI: 10.1016/S0022-1139(00)82238-1

Source and publish data:

Journal of Fluorine Chemistry p. 53 - 60 (1991)

Update date:2022-08-15

Topics:

Authors:

Habibi, Mohammed H.

Mallouk, Thomas E.

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Article abstract of DOI:10.1016/S0022-1139(00)82238-1

Perfluoro-n-butyl iodide reacts photochemically with alkynes and other unsaturated organic compounds to give the corresponding adducts in quantitative yields.The kinetics of addition were studied by 19F-NMR, and indicated that the reaction involves a free radical mechanism.

Full text of DOI:10.1016/S0022-1139(00)82238-1

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