Fluoride as leaving group in SRN1 reactions of a tetrasubstituted-1,4-benzoquinone

DOI: 10.1016/S0040-4039(00)91861-6

Source and publish data:

Tetrahedron Letters p. 1063 - 1064 (1992)

Update date:2022-08-11

Topics:

Authors:

Crozet, Michel P.

Giraud, Luc

Sabuco, Jean-Francois

Vanelle, Patrice

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Article abstract of DOI:10.1016/S0040-4039(00)91861-6

2-Fluoromethyl-3,5,6-trimethyl-1,4-benzoquinone was synthesized and its reactivity in S_RN1 reactions compared to the reactivity of the chloro derivative previously described. This study reports the first examples of the displacement of the fluoride in S_RN1 reactions involving a substitution at an sp³ carbon atom.

Full text of DOI:10.1016/S0040-4039(00)91861-6

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