A Highly Enantioselective Synthesis of (-)-Antirhine by Chemo-Enzymatic Approach

DOI: 10.1016/S0040-4020(01)85357-6

Source and publish data:

Tetrahedron p. 8837 - 8852 (1994)

Update date:2022-08-16

Topics:

Authors:

Danieli, Bruno

Lesma, Giordano

Mauro, Marina

Palmisano, Giovanni

Passarella, Daniele

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Article abstract of DOI:10.1016/S0040-4020(01)85357-6

(-)-Antirhine 2 was synthesized in an efficient and stereocontrolled fashion from the readily available (1R-2S)-cyclohexene dimethanol monoacetate 6.A key step was the regio- and stereoselective Pictet Spengler cyclization of the masked dialdehyde 12 to t

Full text of DOI:10.1016/S0040-4020(01)85357-6

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