
Journal of the Less-Common Metals p. 79 - 89 (1986)
Update date:2022-08-17
Topics:
Hecht
Malm
Carnall
The optical absorption spectra of polycrystalline samples of both alpha - and beta -UF//5 have been measured in the range 2700-500 nm at 4, 77 and about 293 K using a recording spectrophotometer. It was assumed that the crystal field in both cases was dominated by weak covalent interactions; consequently crystal-field analyses were developed based on the angular overlap model. Crystal-field parameters consistent with the experimental data were derived.
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