
Journal of the Chemical Society, Dalton Transactions p. 1883 - 1890 (1993)
Update date:2022-08-12
Topics:
Constable, Edwin C.
Hannon, Michael J.
Tocher, Derek A.
Linking two bipyridine units by a 1,3-phenylene spacer has provided a novel class of ligand which promotes the spontaneous self-assembly of double helicates upon reaction with transition-metal ions.Interaction with copper(I) or silver(I) resulted in dinuclear double-helical complexes with the metal ions occupying pseudo-tetrahedral co-ordination sites.Reaction with cobalt(II) or nickel(II) acetates gave similar dinuclear double-helical structures with a didentate acetate ligand completing the co-ordination sphere of each metal to give a pseudo-octahedral geometry.The crystal structure of
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Doi:10.1021/jo00156a001
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(1971)Doi:10.1002/poc.4182
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(1972)Doi:10.1039/b102285g
(2001)Doi:10.1039/c39760000081
(1976)