Synthesis of Tetrasubstituted Vicinal Difluoroolefines

DOI: 10.1016/00404-0399(50)09345-

Source and publish data:

Tetrahedron Letters p. 5007 - 5010 (1995)

Update date:2022-08-25

Topics:

Authors:

Bildstein, Sylvia

Ducep, Jean-Bernard

Jacobi, Detlef

Zimmermann, Pascale

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Article abstract of DOI:10.1016/00404-0399(50)09345-

Treatment of α-arylthioacetoacetate with DAST afforded a α,β,β-trifluoroester which upon desulfurization followed by HF elimination gave access to tetrasubstituted vicinal diflioroolefines.

Full text of DOI:10.1016/00404-0399(50)09345-

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