Insertion Reactions of the Fragment into a Phosphirene Ring, and Carbonylation of the resulting Rhodium(III) Complex. Crystal and Molecular Structures of Ph(PPh3)2>, O(PPh3)2> and the Novel Dimeric Complex O(PPh3)>2>

DOI: 10.1039/c39920000750

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 750 - 752 (1992)

Update date:2022-08-17

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Authors:

Ajulu, Florence A.

Carmichael, Duncan

Hitchcock, Peter B.

Mathey, Francois

Meidine, Mohamed F.

et al. et al.

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Article abstract of DOI:10.1039/c39920000750

The first example of insertion of the d⁸Rh(I) fragment into a phosphirene ring system results in a five-coordinate Rh(III) complex, which undergoes insertion of carbon monoxide to give either monomeric <O(PPh3)2> or dimeric <<O(PPh3)>2>, the structures of which have been elucidated by NMR spectroscopy and single-crystal X-ray diffraction studies.

Full text of DOI:10.1039/c39920000750

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