Photochemical Behavior of Chlorocarbonylbis(triphenylphosphine)rhodium(I), ClRh(CO)P2 (P = PPh3). Laser Flash Photolysis with Infrared Detection

DOI: 10.1246/cl.1992.747

Source and publish data:

Chemistry Letters p. 747 - 750 (1992)

Update date:2022-08-11

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Authors:

Oishi, Shigero

Kawashima, Takeshi

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Article abstract of DOI:10.1246/cl.1992.747

Laser flash photolysis of ClRh(CO)P2 with monitoring infrared region gave definite evidence of photoelimination of CO, rather than P.ClRhP2 generated reacts with the remaining ClRh(CO)P2 to give a transient binuclear rhodium carbonyl, which regenerates ClRh(CO)P2 via the reaction with CO.

Full text of DOI:10.1246/cl.1992.747

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