Cotrol of Chemical Selectivity by Specific Weak Interactions between Groups in Reacting Molecules

DOI: 10.1246/cl.1988.2037

Source and publish data:

Chemistry Letters p. 2037 - 2040 (1988)

Update date:2022-08-16

Topics:

Authors:

Endo, Tadashi

Suzuki, Takashi

Nakajima, Yutaka

Sakiyama, Yutaka

Takami, Kunihiko

Kato, Jun-ichi

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Article abstract of DOI:10.1246/cl.1988.2037

In oxidation of a pair of associating thiols, each having a phenyl or a given group (R), it has been found that the order of the selectivity agrees with that of the strength of specific R-Ph interactions for each of two sets of R < (i) p-MeC6H4 < Ph < p-MeOC6H4 and (ii) n-C5H11 < Ph < p-MeCOC6H4>.

Full text of DOI:10.1246/cl.1988.2037

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