Asymmetric synthesis of β-hydroxyketones, precursors of chiral 1,3-diols, from β, δ-diketosulfoxides

DOI: 10.1016/S0040-4039(00)91685-X

Source and publish data:

Tetrahedron Letters p. 1605 - 1608 (1992)

Update date:2022-08-02

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Authors:

Solladie

Ghiatou Ghiatou

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Article abstract of DOI:10.1016/S0040-4039(00)91685-X

(R) β, δ-diketosulfoxides were reduced with DIBAL to (S₂R(S)) δ-keto β-hydroxysulfoxides (de>98%) which can be easily transformed into syn or anti chiral 1,3-diols by known procedures.

Full text of DOI:10.1016/S0040-4039(00)91685-X

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Product name:(S)-3-Hydroxy-1-phenyl-4-((R)-toluene-4-sulfinyl)-butan-1-one

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