Small Difference in Cation Stability in Controlling the Formation of Hydrocarbon Salt or Covalent Hydrocarbon

DOI: 10.1246/cl.1992.683

Source and publish data:

Chemistry Letters p. 683 - 686 (1992)

Update date:2022-08-16

Topics:

Authors:

Miyabo, Atsushi

Takeuchi, Ken'ichi

Komatsu, Koichi

Kitagawa, Toshikazu

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Article abstract of DOI:10.1246/cl.1992.683

The reaction of sterically comparable cations, 3-(p-methylphenyl)- and 3-phenyl-1,2-dicyclopropylcyclopropenylium ions with highly stable Kuhn's anion (C67H39^-) gives a hydrocarbon salt and a covalent hydrocarbon, respectively, suggesting that

Full text of DOI:10.1246/cl.1992.683

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