
Tetrahedron Letters p. 2383 - 2386 (1992)
Update date:2022-08-11
Topics:
Heerden, Pieter S. van
Bezuidenhoudt, Barend C. B.
Steenkamp, Jacobus A.
Ferreira, Daneel
Several benzylic copper reagents, BnCu(CN)MgCl, Bn2CuMgCl, BnCu-TMSCl-HMPA, and BnCu-TMSCl-TMEDA, facilitate the conjugate addition of the benzyl ligand to α,b-enones, but only BnCu-TMSCl-TMEDA gave high yields with α,β-unsaturated esters.
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