Tetrahedron Letters p. 7905 - 7908 (1994)
Update date:2022-08-24
Topics:
Baldwin, John E.
Villarica, Karla A.
The (2'-deuterioethenyl)cyclopropanes isomerize to 3-deuteriocyclopentene at 341 deg C with kH/kD = 1.08 and 1.15 for the Z and E isomers, respectively.These normal effects are consistent with 2Z-penten-1,5-diyl diradical transition structures for the isomerization.
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(1994)
