Journal of the Chemical Society. Chemical communications p. 31 - 33 (1986)
Update date:2022-08-10
Topics:
Leeuwen, Piet W. N. M. van
Roobeek, Cornelis F.
Wife, Richard L.
Frijns, John H. G.
Platinum complexes of the general formula Pt(H)(Ph2PO)(Ph2POH)(PPh3) (1a) catalyse the hydroformylation of hept-1-ene and, more significantly, hept-2-ene, yielding products of high linearity (90 and 60percent, respectively); the intermediate alkyl and acyl complexes (1c-e) which most often escape direct observation in a catalytic system, have been successfully isolated and identified.
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