Ru-CATALYZED OXIDATION OF SUBSTITUTED ACETYLENES TO α-KETO ESTERS AND α-KETO AMIDES WITH IODOSYLBENZENE

DOI: 10.1016/S0040-4039(00)88651-7

Source and publish data:

Tetrahedron Letters p. 3661 - 3664 (1982)

Update date:2022-08-16

Topics:

Authors:

Mueller, Paul

Godoy, Jose

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Article abstract of DOI:10.1016/S0040-4039(00)88651-7

Oxidation of alkynyl ethers and -amines with iodosylbenzene in presence of Ru-catalysts affords α-keto esters and α-keto amides in 44-84percent yield.These conversions can also be effected with RuO4.

Full text of DOI:10.1016/S0040-4039(00)88651-7

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