Russian Chemical Bulletin p. 1560 - 1564 (1997)
Update date:2022-08-17
Topics:
Grinberg
Koch
Mazin
Mysov
Sterlin
The possibility of synthesizing dihydromuconic acid by cathodic carboxylation of 1,4-dibromobut-2-ene in the liquid CO2 - aprotic solvent system was investigated. The low yield of dihydromuconic acid in this reaction was explained by the competing reductive debromodimerization and oligomerization of 1,4-dibromobut-2-ene, which lead to the predominant formation of 1,8-dibromo-2,6-octadiene and polymeric products.
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