Accurate determination of the extent to which the SE2′ reactions of an allenylsilane are stereospecifically anti

DOI: 10.1016/S0040-4039(00)77620-9

Source and publish data:

Tetrahedron Letters p. 2383 - 2386 (1993)

Update date:2022-08-17

Topics:

Authors:

Buckle, Michael J. C.

Fleming, Ian

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Article abstract of DOI:10.1016/S0040-4039(00)77620-9

The allenylsilane 1 has been prepared in high enantiomeric purity (98% e.e.); its S_E2′ reaction with adamantyl chloride and isobutyraldehyde are stereospecifically anti to a very high degree (>99:1).

Full text of DOI:10.1016/S0040-4039(00)77620-9

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