Acta Crystallographica, Section C: Crystal Structure Communications p. 1921 - 1924 (1996)
Update date:2022-08-11
Topics:
Lovqvist
The Pt atom has a slightly distorted square-planar coordination in both title compounds, cis-[PtBr2(C2H6OS)2] and trans-[PtI2(C2H6OS)2], with the dimethyl sulfoxide ligands bonded via their S atoms. The bond distances to platinum in the bromo compound are Pt - Br 2.441 (1) and 2.447 (2), and Pt - S 2.254 (2) and 2.245 (2) angstrom, and in the centrosymmetric iodo complex are Pt - I 2.6111 (9) and Pt - S 2.289 (2) angstrom.
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