Stereochemical Aspects on the BF3*Et2O Catalyzed Ring Contraction of 5-Substituted 2,3-Epoxycyclohexanones

DOI: 10.1246/bcsj.65.3206

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3206 - 3208 (1992)

Update date:2022-08-28

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Authors:

Obuchi, Kazuyuki

Hayashibe, Satoshi

Asaoka, Morio

Takei, Hisashi

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Article abstract of DOI:10.1246/bcsj.65.3206

In the BF3*Et2O catalyzed rearrangement of 5-substituted 2,3-epoxycyclohexanones, the stereochemistry of the forming quaternary carbon center was directed by the chirality at 5-position.

Full text of DOI:10.1246/bcsj.65.3206

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