CATHODIC SYNTHESIS OF TETRAALKYLTIN COMPOUNDS.

Article abstract of DOI:10.1149/1.2404026

Methyl bromide and allyl bromide are efficiently reduced at a tin electrode to form tetramethyl and tetraallyl tin. A variety of other bromides with appreciably more negative reduction potentials also produce tetra-substituted tin compounds but the yields are lower. At higher potentials, cathode disintegration is a consequence of the competitive reduction of the carrier electrolyte (Et//4N** plus Br**-).

Full text of DOI:10.1149/1.2404026

Downloaded on 2015-06-01 to IP 134.129.120.3 address. Redistribution subject to ECS terms of use (see ecsdl.org/site/terms_use) unless CC License in place (see abstract).

Downloaded on 2015-06-01 to IP 134.129.120.3 address. Redistribution subject to ECS terms of use (see ecsdl.org/site/terms_use) unless CC License in place (see abstract).

Downloaded on 2015-06-01 to IP 134.129.120.3 address. Redistribution subject to ECS terms of use (see ecsdl.org/site/terms_use) unless CC License in place (see abstract).

Downloaded on 2015-06-01 to IP 134.129.120.3 address. Redistribution subject to ECS terms of use (see ecsdl.org/site/terms_use) unless CC License in place (see abstract).

Downloaded on 2015-06-01 to IP 134.129.120.3 address. Redistribution subject to ECS terms of use (see ecsdl.org/site/terms_use) unless CC License in place (see abstract).