(Diene)Fe(CO)PR3 and X complexes: altered reactivity towards electrophiles and nucleophiles

DOI: 10.1016/0022-328X(88)80505-9

Source and publish data:

Journal of Organometallic Chemistry p. 217 - 222 (1988)

Update date:2022-08-16

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Authors:

Howell, James A. S.

Tirvengadum, Marie-Claire

Walton, Garry

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Article abstract of DOI:10.1016/0022-328X(88)80505-9

Substitution of carbonyl by PPh3 in (diene)Fe(CO)3 complexes changes the regiospecificity of electrophilic attack and provides easier acces to <(allyl)FeL4>X salts.Similar PPh3 substitution in <(dienyl)Fe(CO)3>X complexes results in decreased reactivity t

Full text of DOI:10.1016/0022-328X(88)80505-9

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