Synthesis, crystal structure, dynamic behavior and reactivity of dinaphtho[2,1-b:1',2'-d]phospholes and related atropisomeric phosphacyclic derivatives

Article abstract of DOI:10.1021/jo00100a044

7-Phenyldinaphtho[2,1-b:1',2'-d]phosphole (1b) has been prepared by reaction of dichlorophenylphosphine either with 2,2'-dilithio-1,1'-binaphthalene or with bis-dialin 7. In the latter case the relevant tetrahydro derivative 8 is formed at the same time.