Molecular solid-gas organometallic chemistry. Catalytic and stoichiometric transformations of ethyne at iridium

DOI: 10.1021/om00032a006

Source and publish data:

Organometallics p. 2886 - 2887 (1993)

Update date:2022-08-16

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Authors:

Bianchini, Claudio

Frediani, Piero

Graziani, Mauro

Kaspar, Jan

Meli, Andrea

Peruzzini, Maurizio

Vizza, Francesco

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Article abstract of DOI:10.1021/om00032a006

The η²-ethene dihydride [(triphos)Ir(H)₂-(C₂H₄)]BPh₄ (1; triphos = MeC(CH₂PPh₂)₃) reacts in the solid state with ethyne (4 atm) at 70°C to give five different organome

Full text of DOI:10.1021/om00032a006

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Product name:(CH₃C(CH₂P(C₆H₅)2)3)Ir(C₄H₆)⁽¹⁺⁾*B(C₆H₅)4^(1-)={(CH₃C(CH₂P(C₆H₅)2)3)Ir(C₄H₆)}{B(C₆H₅)4}

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