Cluster synthesis by photolysis of R3PAuN3. Crystal structure of OH and NO3

DOI: 10.1016/0022-328X(89)87077-9

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Journal of Organometallic Chemistry p. 67 - 78 (1989)

Update date:2022-08-02

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Authors:

Beuter, Georg

Straehle, Joachim

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Article abstract of DOI:10.1016/0022-328X(89)87077-9

Photolysis of R3PAuN3 (1) results in a reductive elimination of the azide group yielding R3PAu⁰ moieties which then combine to form Au clusters.In the presence of metal carbonyls heterometalic clusters are obtained.In the case of Mo(CO)6 the ca

Full text of DOI:10.1016/0022-328X(89)87077-9

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