
Journal of the Chemical Society. Chemical communications p. 415 - 416 (1981)
Update date:2022-08-29
Topics:
Farrar, David H.
Jackson, Peter F.
Johnson, Brian F. G.
Lewis, Jack
Nicholls, J. Nicola
McPartlin, Mary
In reaction with CO at 70 deg C and 80 atm the hexanuclear cluster Ru6C(CO)17 undergoes carbonylation, ejects Ru(CO)5 and gives quantitative amounts of Ru5C(CO)15 which X-ray analysis has confirmed has a square-pyramidal Ru5 arrangement with an exposed carbido-atom; some reactions of this pentanuclear cluster are reported together with the X-ray structure analysis of its derivative Ru5C(CO)14PPh3.
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Doi:10.1007/BF00950306
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