
Journal of the Chemical Society. Chemical communications p. 1033 - 1035 (1988)
Update date:2022-08-11
Topics:
Drake, Simon R.
Johnson, Brian F. G.
Lewis, Jack
The chemical activation of iron, ruthenium, and osmium carbonyl cluster anions has been achived by investigating their oxidative electrochemistry and then matching the observed electrochemical oxidation potential with chemical reagents, by the use of oxidative addition in the presence of the required ligand; the dianionic clusters a suitable oxidant.
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