Elimination of β-palladium hydroxide in the PdII-catalyzed reaction of methyl(α-hydroxymethyl)acrylate with alcohols

DOI: 10.1016/0022-328X(94)80175-4

Source and publish data:

Journal of Organometallic Chemistry p. 253 - 256 (1994)

Update date:2022-08-16

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Authors:

Hosokawa, Takahiro

Sugafuji, Toshihiro

Yamanaka, Toshio

Murahashi, Shun-Ichi

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Article abstract of DOI:10.1016/0022-328X(94)80175-4

Exclusive elimination of β-Pd-OH takes place in the oxypalladation intermediate derived from methyl(α-hydroxymethyl)acrylate and alcohols with PdCl2 catalyst, and no β-Pd-H elimination occurs. Key words: Palladium; Hydroxide; Catalysis; Alkene; Mechanism

Full text of DOI:10.1016/0022-328X(94)80175-4

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