Reactions of peroxynitrite with N,N-dimethyl-p-toluidine and 1,4-naphthoquinone. Evidence for heterolytic cleavage of a nitrogen-oxygen bond in peroxynitrous acid

DOI: 10.1016/S0040-4039(99)01239-3

Source and publish data:

Tetrahedron Letters p. 6939 - 6940 (1999)

Update date:2022-08-11

Topics:

Authors:

Nonoyama, Nobuaki

Hisatome, Kaori

Shoda, Chizuru

Suzuki, Hitomi

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Article abstract of DOI:10.1016/S0040-4039(99)01239-3

Peroxynitrite (ONOO^-) has been found to react with the title amine 1 and quinone 5 to form N-nitrosoamine 2 and 2,3-epoxide 6, respectively, in accord with the in situ generation of the nitrosonium and hydroperoxide ions as the respective reactive species.

Full text of DOI:10.1016/S0040-4039(99)01239-3

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