The 'in situ' generation of fluorinated aldehydes and consecutive reactions with P- and N-nucleophiles

DOI: 10.1016/0022-1139(96)03432-x

Source and publish data:

Journal of Fluorine Chemistry p. 75 - 82 (1996)

Update date:2022-08-29

Topics:

Authors:

Haas, Andreas M.

H?gele, Gerhard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-1139(96)03432-x

An optimized method for the generation of fluorinated aldehydes starting from fluorinated carboxylic acid esters is described. The fluorinated aldehydes generated 'in situ' are used to synthesize hitherto unknown fluorinated hydroxyphosphonic acid esters as well as novel fluorinated N-(phenylamino) phosphonic acid esters. The method described here may be used as a 'one-pot synthesis'.

Full text of DOI:10.1016/0022-1139(96)03432-x

Products guided by the article

Product name:DIETHYL (2 2 2-TRIFLUORO-1-HYDROXYETHYL&

Cas No:156748-67-3

R&D Labs maybe for 156748-67-3

GLD peptide scientific lnc.

Contact:21-7631221 15884421033

Address:326 Science and technology,Shanghai,China
Guangxi Bonger Pharmaceutical Co., Ltd

website:http://napo.lookchem.com/

Contact:+86-18817331185

Address:Donghai Industrial Zone, Tiandong Country,Guangxi,China
Hubei Danao Pharmaceutical Co.,Ltd.

website:http://www.danaopharm.com

Contact:+86-719-5251167

Address:Fandan Road,Danjiangkou,Hubei
Shandong Ailitong New Material Co.,Ltd

Contact:+86-536-3226266

Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park

Relevant to this article

Doi:10.1021/ja01234a050
(1944)
Regioselective carbon-carbon bond formation in titanium mediated reaction of ethylmagnesium bromide with allylic alcohols and allylic ethers

Doi:10.1055/s-2001-9707
(2001)
Synthesis and microwave-assisted catalytic activity of novel bis-benzimidazole salts bearing furfuryl and thenylmoieties in heck and suzuki cross-coupling reactions

Doi:10.1002/aoc.1633
(2010)
Investigation of the reaction mechanism and kinetics of production of anhydrous sodium metaborate (NaBO₂) by a solid-state reaction

Doi:10.1007/s11164-012-0580-3
(2013)
Synthesis of chiral calix[n]arenes - I. A synthetic approach towards a new enantiomerically pure calix[8]arene derivative

Doi:10.1016/S0957-4166(96)00513-7
(1997)
Catalytic highly enantioselective transfer hydrogenation of β-trifluoromethyl nitroalkenes. An easy and general entry to optically active β-trifluoromethyl amines

Doi:10.1039/c4cc07801b
(2015)

Article Doi