Bulletin of the Chemical Society of Japan p. 3235 - 3236 (1981)
Update date:2022-08-16
Topics:
Ibaraki, Takeshi
Ito, Katsuko
Iodine monobromide is an extremely effective catalyst for the redistribution of alkoxyl groups on silicon atoms in dimethyldialkoxysilanes.The equilibrium constants of these reactions were determined at 40 deg C by means of gas chromatography.Assuming that the reaction intermediate is the dative form of a dimethyldialkoxysilaneiodine monobromide complex, a mechanism of the reaction was proposed.
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