The Unexpected Regio- and Stereo-specific Diels-Alder Reaction between Cyclopentadiene and 2-Benzenesulphonyl-3-trimethylsilylbicyclohepta-2,5-diene

DOI: 10.1039/c39870000590

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 590 - 591 (1987)

Update date:2022-08-22

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Authors:

Williams, Richard Vaughan

Sung, Chiu-Lien

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Article abstract of DOI:10.1039/c39870000590

The title reaction exhibits remarkable specificity as only one of the eight possible regio- and stereo-isomers is obtained in 98percent yield; the structure of this single adduct is elucidated by chemical degradation.

Full text of DOI:10.1039/c39870000590

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