Nitrone and Nitrile Oxide Cycloadditions to Bicyclopropylidene. Rearrangement of the Isoxazolidine Adducts to 3-Spirocyclopropane-4-pyridone Derivatives

DOI: 10.1039/c39940002185

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2185 - 2186 (1994)

Update date:2022-08-17

Topics:

Authors:

Brandi, Alberto

Goti, Andrea

Kozhushkov, Sergei

Meijere, Armin de

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940002185

The two-step nitrone or nitrile oxide cycloaddition-rearrangement thermal process applied to bicyclopropylidene gives 4-pyridone, 7-indolizinone, and 2-quinolizinone derivatives containing a spirocyclopropane linkage α to a carbonyl group.

Full text of DOI:10.1039/c39940002185

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:8-methyl-9-phenyl-7-oxa-8-azadispiro<2.0.2.3>nonane

Cas No:159555-77-8

R&D Labs maybe for 159555-77-8

Shandong Xinhua Pharmaceutical Co.,Ltd

website:http://www.xhzy.com

Contact:+86-533-2196801

Address:1 lutai road,zhangdian dis,Zibo City
BIOS CHEMICALS

Contact:+33-5-34012600

Address:28 ZA des Pignès
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China
Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City

Relevant to this article

Ionic Liquid Supported on DFNS Nanoparticles Catalyst in Synthesis of Cyclic Carbonates by Oxidative Carboxylation

Doi:10.1007/s10562-021-03616-6
(2021)
Asymmetric hydroazidation of α-substituted vinyl ketones catalyzed by chiral primary amine

Doi:10.1016/j.cclet.2017.01.014
(2017)
Concise and protecting group-free synthesis of botryolide-E

Doi:10.1016/j.tetlet.2012.11.061
(2013)
The big effect of a small change: formation of CuO nanoparticles instead of covalently bound Cu(ii) over functionalized mesoporous silica and its impact on catalytic efficiency

Doi:10.1039/d0dt01922d
(2020)
Recoverable palladium-catalyzed carbon-carbon bond forming reactions under thermomorphic mode: Stille and suzuki-miyaura reactions

Doi:10.3390/molecules26051414
(2021)
Chiral auxiliaries as docking/protecting groups in biohydroxylation: (S)-specific hydroxylation of enantiopure tert-butyl-substituted spirooxazolidines derived from cyclopentanone

Doi:10.1002/ejoc.200400636
(2005)

Article Doi