Reaction of (1-) with the (1+) Cation involving Insertion of an Os(CO)4 Fragment into the Gold-Phosphorus Bond

DOI: 10.1039/DT9940003331

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3331 - 3332 (1994)

Update date:2022-08-17

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Authors:

Cathey, Christopher

Lewis, Jack

Raithby, Paul R.

Ramirez de Arellano, M. Carmen

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Article abstract of DOI:10.1039/DT9940003331

The reaction of the cluster anion (1-) 1 with (1+) affords the cluster (μ-Cl)(CO)10> 2 which represents the first example in which an Os(CO)4 fragment has been inserted in to a gold-phosphine bond; the structure of 2 has been established by a single-crystal X-ray analysis.

Full text of DOI:10.1039/DT9940003331

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