A FACILE HIGH-YIELD SYNTHESIS OF DI-η5-CYCLOPENTADIENYLHAFNACYCLOPENTADIENE COMPOUNDS

DOI: 10.1016/0022-328X(86)80195-4

Source and publish data:

Journal of Organometallic Chemistry p. 311 - 316 (1986)

Update date:2022-08-17

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Authors:

Sabade, Milind B.

Farona, Michael F.

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Article abstract of DOI:10.1016/0022-328X(86)80195-4

Hafnocene dichloride was reduced with amalgamated magnesium in the presence of alkynes giving high yields of di-η⁵-cyclopentadienylhafnacyclopentadienes.Reaction with hydrochloric acid yields exclusively the corresponding (E,E)-butadiene deriva

Full text of DOI:10.1016/0022-328X(86)80195-4

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