Chlorofluorocarbene from Reaction of Fluorotrichloromethane with Reduced Titanium. Synthesis of 1-Chloro-1-fluorocyclopropanes

DOI: 10.1021/jo00289a038

Source and publish data:

Journal of Organic Chemistry p. 589 - 594 (1990)

Update date:2022-08-04

Topics:

Authors:

Dolbier, William R.

Burkholder, Conrad R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00289a038

Generation of chlorofluorocarbene by reaction of CFCl3 with reduced titanium at O deg C, in the presence of various alkenes, produces 1-chloro-1-fluorocyclopropanes in good yield.Evidence from the syn/anti product ratios, including generation of chloroflu

Full text of DOI:10.1021/jo00289a038

Products guided by the article

Product name:Benzene, (2-chloro-2-fluorocyclopropyl)-

Cas No:16084-65-4

R&D Labs maybe for 16084-65-4

jiangsu haian chemical co.,ltd.

Contact:86-513-15851283853

Address:No.99,Changjiang West Road,Haian County,Jiangsu Province,China
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.

Relevant to this article

Bidentate cycloimidate palladium complexes with aliphatic and aromatic anagostic bonds

Doi:10.1039/c4cc01060d
(2014)
Synthesis of a 2-benzazepine analog of a potent, nonpeptide GPIIb/IIIa antagonist

Doi:10.1016/0040-4039(94)02273-E
(1995)
Copper-mediated cascade synthesis of diaryl sulfones via the sandmeyer reaction

Doi:10.1055/s-0033-1340736
(2014)
The oxidative cross-coupling of benzonitriles with multiform substrates: A domino strategy inspired easy access to α-keto-imides

Doi:10.1055/s-0034-1379955
(2015)
2,6-Diaminopurine nucleoside derivative of 9-ethyloxy-2-oxo-1,3- diazaphenoxazine (2-amino-Adap) for recognition of 8-oxo-dG in DNA

Doi:10.1016/j.bmc.2014.01.024
(2014)
Serendipitous oxidation product of BIBN4096BS: A potent CGRP receptor antagonist

Doi:10.1016/j.bmcl.2014.04.033
(2014)

Article Doi